Formation of magnesium silicate hydrate cement in nature

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Silicate chain formation in the nanostructure of cement-based materials.

Cement-based materials are ubiquitous in almost all built environment. In spite of this, little is known about the formation and the role played by the silicate chains always present in the cement nanostructure. By means of first principles simulations we provide compelling evidence on the pivotal role played by certain ionic species in the formation of the silicate chains inside the cementitio...

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Glassy nature of water in an ultraconfining disordered material: the case of calcium-silicate-hydrate.

We present the structural and dynamic nature of water ultraconfined in the quasi-two-dimensional nanopores of the highly disordered calcium-silicate-hydrate (C-S-H), the major binding phase in cement. Our approach is based on classical molecular simulations. We demonstrate that the C-S-H nanopore space is hydrophilic, particularly because of the nonbridging oxygen atoms on the disordered silica...

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Order and disorder in calcium-silicate-hydrate.

Despite advances in the characterization and modeling of cement hydrates, the atomic order in Calcium-Silicate-Hydrate (C-S-H), the binding phase of cement, remains an open question. Indeed, in contrast to the former crystalline model, recent molecular models suggest that the nanoscale structure of C-S-H is amorphous. To elucidate this issue, we analyzed the structure of a realistic simulated m...

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ژورنال

عنوان ژورنال: Journal of the Geological Society

سال: 2017

ISSN: 0016-7649,2041-479X

DOI: 10.1144/jgs2017-089